Give step-by-step solution with explanation and final answer: During electrolysis of molten sodium chloride, a current of 2 amperes is passed for 30 minutes. Calculate the mass of sodium metal deposited at the cathode. (Faraday constant = 96500 C/mol, atomic mass of Na = 23)
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Give step-by-step solution with explanation and final answer: During electrolysis of molten sodium chloride, a current of 2 amperes is passed for 30 minutes. Calculate the mass of sodium metal deposited at the cathode. (Faraday constant = 96500 C/mol, atomic mass of Na = 23)
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Asked by: Rahul
Created at: 2026-01-13 03:10:21
Asked by: Rahul
Created at: 2026-01-13 03:10:21
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# Electrolysis of Molten Sodium Chloride
## Given Data
- **Current (\(I\))**: 2 A
- **Time (\(t\))**: 30 min = 180 s
- **Faraday Constant (\(F\))**: 96500 C/mol
- **Atomic Mass of Na**: 23 g/mol
## Step 1: Write the Cathode Reaction
Molten NaCl dissociates into Na\(^+\) and Cl\(^-\).
At cathode:
\[
\text{Na}^+ + e^- \rightarrow \text{Na}
\]
So, **1 mole of Na** requires **1 mole of electrons** (1 Faraday).
## Step 2: Calculate Total Charge Passed
\[
Q = I \times t = 2\,\text{A} \times 180\,\text{s} = 360\,\text{C}
\]
## Step 3: Calculate Moles of Electrons (Faradays)
\[
\text{Number of Faradays} = \frac{Q}{F} = \frac{360}{96500} \approx .0373\,\text{mol}
\]
## Step 4: Calculate Moles of Sodium Deposited
Since the reaction requires 1 mole of electrons per 1 mole of Na:
\[
\text{Moles of Na deposited} = \text{Moles of electrons} \approx .0373\,\text{mol}
\]
## Step 5: Calculate Mass of Sodium
\[
\text{Mass of Na} = \text{Moles} \times \text{Atomic mass}
\]
\[
= .0373\,\text{mol} \times 23\,\text{g/mol}
\]
\[
= .8579\,\text{g}
\]
## Final Answer
**Mass of sodium deposited at the cathode:**
\[
\boxed{.86\,\text{g}}
\]
(Rounded to two decimal places)
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