Give step-by-step explanation and final answer A vertical flash drum is to flash a liquid of
2
0
0
0
lb moles
/
hr that is
4
0
mol
%
n
-
hexane and
6
0
mol
%
n
-
octane at
1
0
1
.
3
kPa. It is desired to produce a vapor that is
6
0
mol
%
n
-
hexane. Solution of the flash equations with equilibrium data gives x
_
(
H
)
=
0
.
1
9
,
T
_
(
drum
)
=
3
7
8
K
,
(
V
)
/
(
F
)
=
0
.
5
1
.
What size flash drum is required? MW
_
(
H
)
=
8
6
.
1
7
,
density
_
(
H
)
=
0
.
6
5
9
(
g
)
/
(
m
)
L MW
_
(
O
)
=
1
1
4
.
2
2
,
density
_
(
O
)
=
0
.
7
0
3
(
g
)
/
(
m
)
L
1
ft
3
=
2
8
3
1
6
.
8
5
mL
(
consider that the liquid residence time in the flash drum is
1
0
min
)
.
Question:
Give step-by-step explanation and final answer A vertical flash drum is to flash a liquid of
2
0
0
0
lb moles
/
hr that is
4
0
mol
%
n
-
hexane and
6
0
mol
%
n
-
octane at
1
0
1
.
3
kPa. It is desired to produce a vapor that is
6
0
mol
%
n
-
hexane. Solution of the flash equations with equilibrium data gives x
_
(
H
)
=
0
.
1
9
,
T
_
(
drum
)
=
3
7
8
K
,
(
V
)
/
(
F
)
=
0
.
5
1
.
What size flash drum is required? MW
_
(
H
)
=
8
6
.
1
7
,
density
_
(
H
)
=
0
.
6
5
9
(
g
)
/
(
m
)
L MW
_
(
O
)
=
1
1
4
.
2
2
,
density
_
(
O
)
=
0
.
7
0
3
(
g
)
/
(
m
)
L
1
ft
3
=
2
8
3
1
6
.
8
5
mL
(
consider that the liquid residence time in the flash drum is
1
0
min
)
.
This is AI generated Response.
Asked by: Test User 100192
Created at: 2025-05-17 17:07:54
Final Answer:
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Let’s break down the **flash drum sizing** problem step by step.
---
### **Given Data**
- **Feed rate (F):** 2000 lb-moles/hr
- **Feed composition:** 40 mol% n-hexane, 60 mol% n-octane
- **Pressure:** 101.3 kPa
- **Vapor product (yH):** 60 mol% n-hexane
- **Liquid product (xH):** 19 mol% n-hexane
- **Drum temperature:** 378 K
- **V/F (fraction vaporized):** 0.51
- **Molecular weights:**
- n-hexane (MW_H): 86.17
- n-octane (MW_O): 114.22
- **Densities:**
- n-hexane: 0.659 g/mL
- n-octane: 0.703 g/mL
- **1 ft³ = 28316.85 mL**
- **Liquid residence time:** 10 min
---
## **Step 1: Calculate Amount of Liquid and Vapor Products**
Fraction vaporized, \( V/F = 0.51 \Rightarrow V = 0.51F, \ L = F - V = 0.49F \)
- \( F = 2000 \) lb-moles/hr
- \( L = 0.49 \times 2000 = 980 \) lb-moles/hr (liquid out)
- \( V = 0.51 \times 2000 = 1020 \) lb-moles/hr (vapor out)
---
## **Step 2: Calculate Moles of Each Component in Liquid**
**Liquid composition:** \( x_H = 0.19 \) (hexane), \( x_O = 0.81 \) (octane)
- Hexane in liquid: \( 980 \times 0.19 = 186.2 \) lb-moles/hr
- Octane in liquid: \( 980 \times 0.81 = 793.8 \) lb-moles/hr
---
## **Step 3: Mass of Liquid Components per Hour**
- **n-hexane:** \( 186.2 \times 86.17 = 16048 \) lb/hr
- **n-octane:** \( 793.8 \times 114.22 = 90709 \) lb/hr
- **Total mass:** \( 16048 + 90709 = 106757 \) lb/hr
---
## **Step 4: Convert Mass to Grams per Hour**
- \( 1 \) lb \( = 453.592 \) g
- **Total grams/hr:** \( 106757 \times 453.592 = 48431441 \) g/hr
---
## **Step 5: Calculate Volume of Liquid per Hour**
Calculate **average density** of the liquid:
\[
\rho_{avg} = \frac{w_H + w_O}{\frac{w_H}{\rho_H} + \frac{w_O}{\rho_O}}
\]
But since we know masses and densities, calculate **total volume** directly:
- \( V_H = \frac{mass_H}{\rho_H} \)
- \( V_O = \frac{mass_O}{\rho_O} \)
- n-hexane: \( 16048 \) lb/hr \( \times 453.592 = 7286750 \) g/hr
- n-octane: \( 90709 \) lb/hr \( \times 453.592 = 41144691 \) g/hr
\[
V_H = \frac{7286750}{0.659} = 11052228 \text{ mL/hr}
\]
\[
V_O = \frac{41144691}{0.703} = 58527735 \text{ mL/hr}
\]
\[
V_{total} = V_H + V_O = 11052228 + 58527735 = 69579963 \text{ mL/hr}
\]
---
## **Step 6: Calculate Liquid Volume in 10 Minutes (Residence Time)**
- \( 10 \) min \( = \frac{1}{6} \) hr
\[
\text{Volume in 10 min} = \frac{69579963}{6} = 11596660 \text{ mL}
\]
---
## **Step 7: Convert mL to ft³**
\[
\text{Volume in ft}^3 = \frac{11596660}{28316.85} = 409.6 \text{ ft}^3
\]
---
## **Step 8: Final Answer (Rounded)**
### **The required flash drum liquid volume is \(\boxed{410 \ \text{ft}^3}\) (rounded to two significant digits).**
---
### **Summary Table**
| Step | Value | Units |
|------|-------|-------|
| Feed rate | 2000 | lb-moles/hr |
| Liquid out | 980 | lb-moles/hr |
| Liquid mass | 106,757 | lb/hr |
| Liquid mass | 48,431,441 | g/hr |
| Liquid vol/hr | 69,579,963 | mL/hr |
| Liquid vol/10 min | 11,596,660 | mL |
| Liquid vol/10 min | 410 | ft³ |
---
## **Assumptions**
- The liquid product is perfectly mixed.
- The densities are valid at process conditions.
- The flash drum only needs to accommodate the liquid holdup for the residence time (not including vapor space or disengagement volume—those would make the drum larger in practice).
---
**If you need to account for vapor disengagement space or want to size the drum diameter/height, let me know!**
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