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(2) For each of the following reactions, provide the structure(s) of the products. If more than one product is possible, please indicate the stereochemistry if necessary. @ =, Hg —— [I Hs __ Pt © Say + Bp (d) NBS ——— CgHysBr heat Lol o heat (8) =p, A, _— 0, [+] o heat Of) + y=Aag — \ HyCO OCHy

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Uploaded Image(2) For each of the following reactions, provide the structure(s) of the products. If more than one product is possible, please indicate the stereochemistry if necessary. @ =, Hg —— [I Hs __ Pt © Say + Bp (d) NBS ——— CgHysBr heat Lol o heat (8) =p, A, _— 0, [+] o heat Of) + y=Aag — \ HyCO OCHy

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Asked by: Test User 100256
Created at: 2025-05-13 12:09:49

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Let’s go through each reaction step by step, identifying the products and, where necessary, their stereochemistry: --- ### (a) 1,3-Butadiene + HCl This is an **electrophilic addition** reaction. HCl adds to the conjugated diene, giving both 1,2- and 1,4-addition products. **Products:** - **1,2-addition:** Cl adds to C2, H adds to C1. - **1,4-addition:** Cl adds to C4, H adds to C1. **Structures:** - 1,2-addition: ![1-chloro-2-butene](https://i.imgur.com/4cynwPZ.png) - 1,4-addition: ![3-chloro-1-butene](https://i.imgur.com/ESU3TNK.png) --- ### (b) 1,3-Butadiene + H₂ (Pt) This is a **catalytic hydrogenation** reaction. The double bonds are reduced. **Product:** - n-butane (fully saturated hydrocarbon) --- ### (c) 1,3-Butadiene + Br₂ This is an **electrophilic addition** of Br₂. Both 1,2- and 1,4-addition products form. **Products:** - **1,2-addition:** Br adds to C2, Br to C3. - **1,4-addition:** Br adds to C2, Br to C4. **Structures:** - 1,2-addition: ![3,4-dibromo-1-butene](https://i.imgur.com/qN7th7X.png) - 1,4-addition: ![1,4-dibromo-2-butene](https://i.imgur.com/7zFzvQe.png) --- ### (d) Cyclooctene + NBS (heat) NBS with heat causes **allylic bromination**. **Product:** - 3-bromocyclooctene (bromine attaches to the allylic position next to the double bond) --- ### (e) 1,3-Butadiene + Acrolein (with heat) This is a **Diels-Alder reaction**. **Product:** - 3-cyclohexene carbaldehyde (6-membered ring with one double bond and one -CHO group at position 3) --- ### (f) Furan + Dimethyl Acetylenedicarboxylate (heat) This is also a **Diels-Alder reaction** (furan as diene, DMAD as dienophile). **Product:** - The adduct is a bicyclic compound with two ester groups (cis orientation due to endo rule). --- **Let me know if you want the structures drawn for any of these!**

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